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Much of the Earth's geology consists of successional layers of different rock types, piled one on top of another.
The most common rocks observed in this form are sedimentary rocks (derived from what were formerly sediments), and extrusive igneous rocks (e.g., lavas, volcanic ash, and other formerly molten rocks extruded onto the Earth's surface).
As an example of how they are used, radiometric dates from geologically simple, fossiliferous Cretaceous rocks in western North America are compared to the geological time scale.
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It can't float in mid-air, particularly if the material involved is sand, mud, or molten rock.
The principle of superposition therefore has a clear implication for the age of a vertical succession of strata.
Despite this, the "principle of cross cutting relationships" can be used to determine the sequence of deposition, folds, and faults based on their intersections -- if folds and faults deform or cut across the sedimentary layers and surfaces, then they obviously came after deposition of the sediments.
You can't deform a structure (e.g., bedding) that is not there yet!
The example used here contrasts sharply with the way conventional scientific dating methods are characterized by some critics (for example, refer to discussion in "Common Creationist Criticisms of Mainstream Dating Methods" in the Age of the Earth FAQ and Isochron Dating FAQ).